141 A toxin obtained from a plant, animal, or bacterial source containing an infectious substance, or a toxin contained in an infectious substance, must be classed as Division 6.2, described as an infectious substance, and assigned to UN 2814 or UN 2900, as appropriate. These provisions apply only to transportation in IBCs and Large Packagings. A37 This entry applies only to a material meeting the definition in 171.8 of this subchapter for self-defense spray. Nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel are not subject to the requirements of this special provision. 163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR, see 171.7 of this subchapter). 31 Materials which have undergone sufficient heat treatment to render them non-hazardous are not subject to the requirements of this subchapter. 391 Except for articles being transported by motor vehicle as a material of trade in accordance with 173.6 of this subchapter, articles containing hazardous materials of Division 2.3, or Division 4.2, or Division 4.3, or Division 5.1, or Division 5.2, or Division 6.1 (substances with an inhalation toxicity of Packing Group I) and articles containing more than one of the following hazards: (1) Gases of Class 2; (2) Liquid desensitized explosives of Class 3; or (3) Self-reactive substances and solid desensitized explosives of Division 4.1, may only be offered for transportation and transported under conditions approved by the Associate Administrator. TP10 A lead lining, not less than 5 mm thick, which shall be tested annually, or another suitable lining material approved by the competent authority, is required. 125 Lactose or glucose or similar materials may be used as a phlegmatizer provided that the substance contains not less than 90%, by mass, of phlegmatizer. (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 C (115 F). These special provisions are in addition to the standard packaging requirements. A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. 110 Fire extinguishers transported under UN1044 and oxygen cylinders transported for emergency use under UN1072 may include installed actuating cartridges (cartridges, power device of Division 1.4C or 1.4S), without changing the classification of Division 2.2, provided the aggregate quantity of deflagrating (propellant) explosives does not exceed 3.2 grams per cylinder. Tables 1, 2, and 3 follow: 1 Flexible plastic (51H) Large Packagings are only authorized for use with flexible inner packagings. N73 Packagings consisting of outer wooden or fiberboard boxes with inner glass, metal or other strong containers; metal or fiber drums; kegs or barrels; or strong metal cans are authorized and need not conform to the requirements of part 178 of this subchapter. Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. TP21 The wall thickness must not be less than 8 mm. TP32 Portable tanks may be used subject to the following conditions: a. B130 When transported by motor vehicle, used diatomaceous earth filter material is not subject to any other requirements of this subchapter except for the shipping paper requirements of subpart C of part 172 of this subchapter; emergency response information as required by 172.602(a)(2) through (a)(7) of this subchapter; and the marking requirements of 172.302 of this subchapter, if the following requirements are met: a. Packagings are non-DOT specification sift-proof motor vehicles or sift-proof roll-on/roll-off bulk bins, which are covered by a tarpaulin or other equivalent means. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. If you have questions or comments regarding a published document please 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. A lighter refill exceeding 4 fluid ounces capacity (7.22 cubic inches) or containing more than 65 grams of fuel must be classed as a Division 2.1 material, described with the proper shipping name appropriate for the material, and packaged in the packaging specified in part 173 of this subchapter for the flammable gas contained therein. 49 CFR 172.101 N41 Metal construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. Overcharge of the rechargeable lithium ion cells is precluded by design; iii. Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 6.35 mm (0.250 inch) or the thickness required for a tank with a design pressure at least equal to 1.3 times the vapor pressure of the lading at 46 C (115 F). Examples of such vehicles are electrically-powered cars, motorcycles, scooters, three- and four-wheeled vehicles or motorcycles, trucks, locomotives, bicycles (pedal cycles with an electric motor) and other vehicles of this type (e.g., self-balancing vehicles or vehicles not equipped with at least one seating position), lawn tractors, self-propelled farming and construction equipment, boats, aircraft, wheelchairs and other mobility aids. Effective January 1, 2012, for transportation by vessel, this entry may only be used if the results of Test Series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. These provisions can be classified even further with each form of transportation. 123 Any explosives, blasting, type C containing chlorates must be segregated from explosives containing ammonium nitrate or other ammonium salts. 19 For domestic transportation only, the identification number UN1075 may be used in place of the identification number specified in column (4) of the 172.101 table. 65 The group of alkaline earth metals includes magnesium, calcium, strontium, and barium. The consignor shall be in possession of a copy of each applicable certificate when packages include fissile material excepted by competent authority approval. Note that batteries utilizing different chemistries (i.e., those battery chemistries specifically covered by another entry in the 172.101 Table) as well as dry batteries with a marked rating greater than 9-volt may not be combined with used or spent batteries in the same package. 351 Ammonium chlorate, ammonium chlorate aqueous solutions, and mixtures of a chlorate with an ammonium salt are forbidden for transport. A stimulating mechanism must be used to initiate one article in the middle of the packaging. Batteries contained in devices must be securely installed. b. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). N83 This material may not be transported in quantities of more than 11.5 kg (25.4 lbs) per package. Compressed air containing greater than 23.5 percent oxygen must be shipped using the description Compressed gas, oxidizing, n.o.s., UN3156.. For UN 3176, this requirement only applies when the hazardous material reacts dangerously with water. f. The properties of mechanical strength mentioned in this special provision shall be tested using a prototype of a receptacle and/or dispenser filled to nominal capacity, by increasing the temperature until the specified pressures are reached. All successfully conducted tests or reassignment to another compatibility group require the issuance of a new or revised approval by the Associate Administrator prior to transportation on or after the dates specified for each authorized mode of transport in this special provision. Fertilizers meeting the criteria for this identification number are only subject to the requirements of this subchapter when offered for transportation and transported by air or vessel. A200 These articles must be transported as cargo and may not be carried aboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically authorized in 175.10. TP26 The heating device must be exterior to the shell. The lithium batteries must meet the requirements of 173.185(a) and contain the necessary systems to prevent overcharge and over discharge between the batteries. Component cells of the battery must be of a type proved to meet the respective testing requirements of the Manual of Tests and Criteria, part III, subsection 38.3 (IBR, see 171.7 of this subchapter). TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. Except as provided in 173.185(c)(3) of this subchapter, the package must be marked UN 3091 Lithium metal batteries packed with equipment, or UN 3481 Lithium ion batteries packed with equipment, as appropriate. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. (v) The box must be constructed from high-density polyethylene in the density range 0.950-0.962, and be capable of holding liquid when in the upright position. 164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of this subchapter. The Associate Administrator may except from the requirements of this subchapter articles, machinery, and apparatus provided: a. Formulations not meeting these criteria must be transported under the provisions applicable to the appropriate entry in the Organic Peroxide Table in 173.225 of this subchapter. If a vehicle is powered by a flammable liquid and a flammable gas internal combustion engine, it must be described using Vehicle, flammable gas powered. This includes hybrid electric vehicles powered by both an internal combustion engine and wet, sodium or lithium batteries installed. When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. Terminal protection methods include but are not limited to the following: (i) Securely attaching covers of sufficient strength to protect the terminals; (ii) Packaging the battery in a rigid plastic packaging; or. The cargo transport unit shall display the UN number in a manner in accordance with 172.332 of this subchapter and be placarded on two opposing sides. No Class 7 label is required to be displayed. In addition, there are over 300 numeric codes provisions. 151 If this material meets the definition of a flammable liquid in 173.120 of this subchapter, a FLAMMABLE LIQUID label is also required and the basic description on the shipping paper must indicate the Class 3 subsidiary hazard. 40 Polyester resin kits consist of two components: A base material (either Class 3 or Division 4.1, Packing Group II or III) and an activator (organic peroxide), each separately packed in an inner packaging. B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. B115 Rail cars, highway trailers, roll-on/roll-off bins, or other non-specification bulk packagings are authorized. Based on the volatility class determined by using ASTM D 439 and the Reid vapor pressure (RVP) of the particular gasoline, the maximum lading pressure and maximum ambient temperature permitted during the loading of gasoline may not exceed that listed in Table I. contact the publishing agency. 130 Batteries, dry, sealed, n.o.s., commonly referred to as dry batteries, are hermetically sealed and generally utilize metals (other than lead) and/or carbon as electrodes. When such batteries are transported in accordance with 173.185(c), the total lithium content of all lithium metal cells contained in the battery must not exceed 1.5 g and the total capacity of all lithium ion cells contained in the battery must not exceed 10 Wh. The quantities of hazardous materials do not exceed those specified in 173.4a of this subchapter; and. These notes are explained at the end of each TABLE. These batteries are typically used for portable power applications. TP9 A hazardous material assigned to special provision TP9 in Column (7) of the 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. b. 13 The words Inhalation Hazard shall be entered on each shipping paper in association with the shipping description, shall be marked on each non-bulk package in association with the proper shipping name and identification number, and shall be marked on two opposing sides of each bulk package. The packaging shall be designed for a working temperature of at least 121 C (250 F). is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. 43 The membrane filters, including paper separators and coating or backing materials, that are present in transport, must not be able to propagate a detonation as tested by one of the tests described in the UN Manual of Tests and Criteria, Part I, Test series 1(a) (IBR, see 171.7 of this subchapter). c. Primary receptacles may also be further packed in specification bulk outer packagings. 387 When materials are stabilized by temperature control, the provisions of 173.21(f) of this subchapter apply. They will appear as a list of codes that are defined in 172.102 of the Code of Federal Regulations. 16 This description applies to smokeless powder and other solid propellants that are used as powder for small arms and have been classed as Division 1.3C, 1.4C and Division 4.1 in accordance with 173.56 of this subchapter. Lading in unlined tanks must be inhibited so that the corrosive effect on steel is not greater than that of hydrofluoric acid of 65 percent concentration. (In the example, the special provision codes for toluene are IB2, T4 and TP1.) b. This particularly applies to corrosivity, permeability, softening, premature aging and embrittlement. The toy plastic or paper caps must be in the form of sheets, strips, rolls, or individual caps; b. 1/1.1 81 Polychlorinated biphenyl items, as defined in 40 CFR 761.3, for which specification packagings are impractical, may be packaged in non-specification packagings meeting the general packaging requirements of subparts A and B of part 173 of this subchapter. In addition, MC 312 and DOT 412 cargo tank motor vehicles must: c. Have a MAWP or design pressure of at least 87 psig; and. If the SADT of the technically pure substance is higher than 75 C, the technically pure substance and formulations derived from it are not self-reactive materials and, if not meeting any other hazard class, are not subject to the requirements of this subchapter. (i) Column 8: Packaging authorizations. The proper shipping name Paint related material, corrosive, flammable may be used for consignments of packages containing Paint, corrosive, flammable and Paint related material, corrosive, flammable in the same package; c. The proper shipping name Paint related material, flammable, corrosive may be used for consignments of packages containing Paint, flammable, corrosive and Paint related material, flammable, corrosive in the same package; and. A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries. This is an automated process for This includes vehicles transported in a packaging. For this test, the provisions of paragraphs 16.6.1.2 except letter g, 16.6.1.3.1 to 16.6.1.3.6, 16.6.1.3.7(b) and 16.6.1.3.8 of the UN Manual of Tests and Criteria must be applied. The adsorbent or absorbent material shall not meet the definition or criteria for inclusion in Classes 1 to 8; c. The maximum contents of a receptacle shall be 10 kg of ammonia; and. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. Each inner packaging contains not more than 30 mL; b. Dry batteries not specifically covered by another entry in the 172.101 Table are covered by this entry (i.e., Batteries, dry, sealed, n.o.s.) Net weight of contents may not exceed 15 kg (33 pounds). b. (a) General. N37 This material may be shipped in an integrally-lined fiber drum (1G) which meets the general packaging requirements of subpart B of part 173 of this subchapter, the requirements of part 178 of this subchapter at the packing group assigned for the material and to any other special provisions of column 7 of the 172.101 table. Learn more about the eCFR, its status, and the editorial process. Column 7: Special provisions. This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. When a special provision specifies packaging or packaging requirements - (h) Column 7: Special provisions. N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. 46 This material must be packed in accordance with packing method OP6 (see 173.225 of this subchapter). The standards for transporting a single bulk hazardous material for blasting by cargo tank motor vehicles (CTMV); and. 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. 379 When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. The identification number used must be consistent on package markings, shipping papers and emergency response information. This entry does not apply to capacitors that by design maintain a terminal voltage (e.g., asymmetrical capacitors.). W7 Vessel stowage category for uranyl nitrate hexahydrate solution is D as defined in 172.101(k)(4). On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. meet the venting requirements in 173.24(g) or (2.) The packing group assignment and packaging must be approved by the Associate Administrator for Hazardous Materials Safety on the basis of the criteria in 173.21 of this subchapter and the package type used for the Series 6(c) test. Table I - Maximum Ambient Temperature - Gasoline. in Column (7) of the 172.101 Hazardous Materials Table for a specific haz-ardous material; and marine portable tanks conforming to 46 CFR part 64 are authorized. (eg: 70 Black powder that has been classed in accordance with the requirements of 173.56 of this subchapter may be reclassed and offered for domestic transportation as a Division 4.1 material if it is offered for transportation and transported in accordance with the limitations and packaging requirements of 173.170 of this subchapter.
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